[1]周毅,甘云华,杨泽亮.采用多元非线性回归法的生物柴油动力学分析[J].哈尔滨工程大学学报,2020,41(7):1036-1042.[doi:10.11990/jheu.201902020]
 ZHOU Yi,GAN Yunhua,YANG Zeliang.Kinetic analysis of biodiesel based on multivariate nonlinear regression method[J].hebgcdxxb,2020,41(7):1036-1042.[doi:10.11990/jheu.201902020]
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采用多元非线性回归法的生物柴油动力学分析(/HTML)
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《哈尔滨工程大学学报》[ISSN:1006-6977/CN:61-1281/TN]

卷:
41
期数:
2020年7期
页码:
1036-1042
栏目:
出版日期:
2020-07-05

文章信息/Info

Title:
Kinetic analysis of biodiesel based on multivariate nonlinear regression method
作者:
周毅12 甘云华12 杨泽亮12
1. 华南理工大学 电力学院, 广东 广州 510640;
2. 广东省能源高效清洁利用重点实验室, 广东 广州 510640
Author(s):
ZHOU Yi12 GAN Yunhua12 YANG Zeliang12
1. School of Electric Power Engineering, South China University of Technology, Guangzhou 510640, China;
2. Guangdong Provincial Key Laboratory of Efficient and Clean Energy Utilization, Guangzhou 510640, China
关键词:
生物柴油动力学热解热重分析动力学模型多元非线性回归傅里叶红外光谱升温速率
分类号:
TK16
DOI:
10.11990/jheu.201902020
文献标志码:
A
摘要:
针对目前生物柴油的燃烧和热解动力学分析不够完善,本文采用热重分析仪-傅里叶红外变换光谱仪联用对生物柴油分别进行氮气和空气气氛下不同升温速率的实验,并分析所得到的热重-热失重速率(TG-DTG)曲线与红外光谱图。利用Kissinger法和Starink法分别计算出生物柴油在不同气氛下的活化能与指前因子。以无模式函数法所求解的动力学参数作为初值,通过多元非线性回归法求出相符的机理函数,并进行F-检验以验证其回归良好。结果表明:生物柴油热解和燃烧热重-热失重速率的曲线变化规律一致,皆随升温速率的提高而向高温区移动,且最大失重速率点接近;热解和燃烧过程中气态产物基本一致,仅在燃烧过程中在2 250~2 000 cm-1处检测到一氧化碳的特征峰;多元非线性回归法分析得出生物柴油热解过程为单步动力学反应,燃烧过程为两步连续动力学反应。实验分析和回归求出的机理函数,可用于生物柴油燃烧和热解过程的化学反应动力学特性预测。

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备注/Memo

备注/Memo:
收稿日期:2019-02-22。
基金项目:国家自然科学基金项目(51776077);广东省基础与应用基础研究基金项目(2020B1515020040);华南理工大学中央高校基本科研业务费资助项目(2018ZD05).
作者简介:周毅,男,硕士研究生;甘云华,男,教授,博士生导师.
通讯作者:甘云华,E-mail:ganyh@scut.edu.cn.
更新日期/Last Update: 2020-08-15